Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
1
pubmed:dateCreated
2007-2-20
pubmed:abstractText
The formation of secondary products during the ozone-initiated oxidations with biogenic VOCs emitted from natural paint was investigated in this study. Mass spectrometry and infrared spectroscopy measurements have shown that the major components of gas-phase chemicals emitted from natural paint are monoterpenes including alpha- and beta-pinenes, camphene, p-cymene, and limonene. A significant formation of gaseous carbonyl products and nano-sized particles (4.4-168nm) was observed in the presence of ozone. Carboxylic acids were also observed to form during the reactions (i.e. formic acid at 0.170ppm and acetic acid at 0.260ppm). The formation of particles increased as the volume of paint introduced into a reaction chamber increased. A secondary increase in the particle number concentration was observed after 440min, which suggests further partitioning of oxidation products (i.e. carboxylic acids) into the particles previously existing in the reaction chamber. The growth of particles increased as the mean particle diameter and particle mass concentrations increased during the reaction. The experimental results obtained in this study may provide insight into the potential exposure of occupants to irritating chemical compounds formed during the oxidations of biogenic VOCs emitted from natural paint in indoor environments.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Mar
pubmed:issn
0304-3894
pubmed:author
pubmed:issnType
Print
pubmed:day
6
pubmed:volume
141
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
245-51
pubmed:meshHeading
pubmed:year
2007
pubmed:articleTitle
The formation of ultra-fine particles during ozone-initiated oxidations with terpenes emitted from natural paint.
pubmed:affiliation
Department of Civil and Environmental Engineering, Korea Advanced Institute of Science and Technology, 373-1 Guseong-Dong, Yuseong-Gu, Daejeon 305-701, Republic of Korea.
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't