Linked Life Data

16847618

Source:http://linkedlifedata.com/resource/pubmed/id/16847618

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
2
pubmed:dateCreated
2006-8-31
pubmed:abstractText
A quantitative method for the determination of Dacthal and its di-acid metabolite in soil has been developed by coupling ultrasound-assisted extraction and microwave-assisted derivatization of the analytes prior to gas chromatography-electron capture detection for individual separation and measurement. The main factors affecting both extraction efficiency and derivatization were optimized by experimental design methodology. The proposed approach allows extraction of these pollutants from spiked sediment and soil with efficiencies similar to those provided by the reference method but with a drastic reduction of both the extraction and derivatization times. The repeatability of the analyses, expressed as RSD, of Dacthal and its di-acid metabolite was 4.6% and 5.4%, respectively; meanwhile, the RSD for within-laboratory reproducibility was 8.7% and 9.2%, respectively.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Sep
pubmed:issn
1618-2642
pubmed:author
pubmed:issnType
Print
pubmed:volume
386
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
341-5
pubmed:meshHeading
pubmed:year
2006
pubmed:articleTitle
Gas chromatography-electron capture detection determination of Dacthal and its di-acid metabolite in soil after ultrasound-assisted extraction and in situ focused microwave-assisted derivatization.
pubmed:affiliation
Department of Analytical Chemistry, Marie Curie Building (Annex), Rabanales Campus, University of Córdoba, Córdoba 14071, Spain.
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't