rdf:type |
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lifeskim:mentions |
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pubmed:issue |
15
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pubmed:dateCreated |
2006-7-14
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pubmed:abstractText |
The palladium acetate-catalyzed coupling reaction of aryl boronic acid with carboxylic anhydride or acyl chloride was carried out smoothly in water in the presence of poly(ethylene glycol) (PEG) or 1-butyl-3-methylimidazolium hexafluorophosphate ([bmim][PF6]) to give high yields of ketones without the use of phosphine ligands. The Pd(OAc)2-H2O-[bmim][PF6] catalytic system can be recovered and reused eight times with high efficiency for both carboxylic anhydride and acyl chloride.
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pubmed:language |
eng
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pubmed:journal |
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pubmed:citationSubset |
IM
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pubmed:chemical |
http://linkedlifedata.com/resource/pubmed/chemical/Anhydrides,
http://linkedlifedata.com/resource/pubmed/chemical/Boronic Acids,
http://linkedlifedata.com/resource/pubmed/chemical/Carboxylic Acids,
http://linkedlifedata.com/resource/pubmed/chemical/Chlorides,
http://linkedlifedata.com/resource/pubmed/chemical/Hydrocarbons, Halogenated,
http://linkedlifedata.com/resource/pubmed/chemical/Ketones,
http://linkedlifedata.com/resource/pubmed/chemical/Organometallic Compounds,
http://linkedlifedata.com/resource/pubmed/chemical/Palladium,
http://linkedlifedata.com/resource/pubmed/chemical/Phosphines,
http://linkedlifedata.com/resource/pubmed/chemical/Polyethylene Glycols,
http://linkedlifedata.com/resource/pubmed/chemical/phosphine
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pubmed:status |
MEDLINE
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pubmed:month |
Jul
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pubmed:issn |
0022-3263
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pubmed:author |
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pubmed:issnType |
Print
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pubmed:day |
21
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pubmed:volume |
71
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
5725-31
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pubmed:meshHeading |
pubmed-meshheading:16839154-Anhydrides,
pubmed-meshheading:16839154-Boronic Acids,
pubmed-meshheading:16839154-Carboxylic Acids,
pubmed-meshheading:16839154-Catalysis,
pubmed-meshheading:16839154-Chlorides,
pubmed-meshheading:16839154-Hydrocarbons, Halogenated,
pubmed-meshheading:16839154-Ketones,
pubmed-meshheading:16839154-Molecular Structure,
pubmed-meshheading:16839154-Organometallic Compounds,
pubmed-meshheading:16839154-Palladium,
pubmed-meshheading:16839154-Phosphines,
pubmed-meshheading:16839154-Polyethylene Glycols
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pubmed:year |
2006
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pubmed:articleTitle |
Phosphine-free cross-coupling reaction of arylboronic acids with carboxylic anhydrides or acyl chlorides in aqueous media.
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pubmed:affiliation |
Department of Chemistry, Zhejiang University, Hangzhou 310027, P.R. China.
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pubmed:publicationType |
Journal Article,
Research Support, U.S. Gov't, Non-P.H.S.
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