Linked Life Data

16833513

Source:http://linkedlifedata.com/resource/pubmed/id/16833513

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
9
pubmed:dateCreated
2006-7-12
pubmed:abstractText
One- and two-color, mass selected R2PI spectra of the S(1) <-- S(0) transitions in the bare (R)-(+)-1-phenyl-1-propanol and its complexes with bidentate solvent molecules, like the (R)-(-)- and (S)-(+)-3-hydroxytetrahydrofuran enantiomers, have been recorded after a supersonic molecular beam expansion. The one-color R2PI excitation spectra of the diastereomeric complexes are characterized by three main peaks, one red-shifted and the other two blue-shifted relative to the band origin of the most stable anti conformer of the bare chromophore. The opposite direction of these spectral shifts is ascribed to the occurrence of three different hydrogen bonded isomeric structures for each individual complex, while their different magnitude depends on the configuration of the bidentate solvent molecule as well as its specific hydrogen bond interaction center, whether the ethereal oxygen atom or the hydroxyl group. The same factors play a major role in determining the magnitude of the phenomenological activation barriers for the loss of an ethyl radical from the ionized diastereomeric complexes.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Mar
pubmed:issn
1089-5639
pubmed:author
pubmed:issnType
Print
pubmed:day
10
pubmed:volume
109
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
1828-35
pubmed:year
2005
pubmed:articleTitle
Excitation, ionization, and fragmentation of chiral molecules in asymmetric microenvironments: a mass-resolved R2PI spectroscopic study.
pubmed:affiliation
Dipartimento di Scienze e Tecnologie Chimiche, Università degli Studi di Roma Tor Vergata, Roma, Italy.
pubmed:publicationType
Journal Article