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pubmed-article:16805539pubmed:abstractText[reaction: see text] Azophenol dyes having the permethylated cyclodextrin and/or crown moieties have been synthesized. Compound 1 provides critical information on discriminating 1-3 degrees amines with unique color changes. Addition of 1 degrees and 2 degrees amines to 1 shifts the absorbance maximum of 1 from 380 to approximately 580 and approximately 530 nm, respectively, but no change is observed with 3 degrees amines. The high selectivity of 1 is mainly due to H-bonding between the ammonium H atoms of the amine and oxygen atoms of the crown-6.lld:pubmed
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pubmed-article:16805539pubmed:authorpubmed-author:SakataYoshite...lld:pubmed
pubmed-article:16805539pubmed:authorpubmed-author:KimJong...lld:pubmed
pubmed-article:16805539pubmed:authorpubmed-author:LeeSoo JinSJlld:pubmed
pubmed-article:16805539pubmed:authorpubmed-author:JungJong...lld:pubmed
pubmed-article:16805539pubmed:authorpubmed-author:LeeWoo SongWSlld:pubmed
pubmed-article:16805539pubmed:authorpubmed-author:KanedaTakahir...lld:pubmed
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pubmed-article:16805539pubmed:dateRevised2007-12-3lld:pubmed
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pubmed-article:16805539pubmed:articleTitlealpha-CD/crown-appended diazophenol for selective sensing of amines.lld:pubmed
pubmed-article:16805539pubmed:affiliationDepartment of Chemistry, Gyeongsang National University, Chinju, Korea. jonghwa@gnu.ac.krlld:pubmed
pubmed-article:16805539pubmed:publicationTypeJournal Articlelld:pubmed
pubmed-article:16805539pubmed:publicationTypeResearch Support, N.I.H., Extramurallld:pubmed
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