Source:http://linkedlifedata.com/resource/pubmed/id/16805539
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Predicate | Object |
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
14
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pubmed:dateCreated |
2006-6-29
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pubmed:abstractText |
[reaction: see text] Azophenol dyes having the permethylated cyclodextrin and/or crown moieties have been synthesized. Compound 1 provides critical information on discriminating 1-3 degrees amines with unique color changes. Addition of 1 degrees and 2 degrees amines to 1 shifts the absorbance maximum of 1 from 380 to approximately 580 and approximately 530 nm, respectively, but no change is observed with 3 degrees amines. The high selectivity of 1 is mainly due to H-bonding between the ammonium H atoms of the amine and oxygen atoms of the crown-6.
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pubmed:grant | |
pubmed:language |
eng
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pubmed:journal | |
pubmed:citationSubset |
IM
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pubmed:chemical | |
pubmed:status |
MEDLINE
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pubmed:month |
Jul
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pubmed:issn |
1523-7060
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pubmed:author | |
pubmed:issnType |
Print
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pubmed:day |
6
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pubmed:volume |
8
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
3009-12
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pubmed:dateRevised |
2007-12-3
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pubmed:meshHeading | |
pubmed:year |
2006
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pubmed:articleTitle |
alpha-CD/crown-appended diazophenol for selective sensing of amines.
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pubmed:affiliation |
Department of Chemistry, Gyeongsang National University, Chinju, Korea. jonghwa@gnu.ac.kr
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pubmed:publicationType |
Journal Article,
Research Support, N.I.H., Extramural
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