Source:http://linkedlifedata.com/resource/pubmed/id/16805538
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Predicate | Object |
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
14
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pubmed:dateCreated |
2006-6-29
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pubmed:abstractText |
[reaction: see text] A series of modified gamma-cyclodextrins (CDs) with a flexible or rigid cap, synthesized and used as chiral supramolecular hosts for mediating the enantiodifferentiating photocyclodimerization of 2-anthracenecarboxylic acid, significantly improved the chemical and optical yields of chiral head-to-head cyclodimer 3, while the gamma-CD with a rigid cap dramatically inverted the stereochemical outcomes and further improved the enantioselectivities of both head-to-tail and head-to-head dimers 2 and 3.
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pubmed:language |
eng
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pubmed:journal | |
pubmed:citationSubset |
IM
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pubmed:chemical | |
pubmed:status |
MEDLINE
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pubmed:month |
Jul
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pubmed:issn |
1523-7060
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pubmed:author | |
pubmed:issnType |
Print
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pubmed:day |
6
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pubmed:volume |
8
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
3005-8
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pubmed:meshHeading |
pubmed-meshheading:16805538-Anthracenes,
pubmed-meshheading:16805538-Carboxylic Acids,
pubmed-meshheading:16805538-Dimerization,
pubmed-meshheading:16805538-Models, Molecular,
pubmed-meshheading:16805538-Molecular Structure,
pubmed-meshheading:16805538-Photochemistry,
pubmed-meshheading:16805538-Stereoisomerism,
pubmed-meshheading:16805538-gamma-Cyclodextrins
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pubmed:year |
2006
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pubmed:articleTitle |
Enantiodifferentiating photocyclodimerization of 2-anthracenecarboxylic acid mediated by gamma-cyclodextrins with a flexible or rigid cap.
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pubmed:affiliation |
ICORP Entropy Control Project, JST, Toyonaka, Japan.
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pubmed:publicationType |
Journal Article
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