Linked Life Data

16791904

Source:http://linkedlifedata.com/resource/pubmed/id/16791904

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
26
pubmed:dateCreated
2006-9-4
pubmed:abstractText
Electronic origin for nonresonant enhancement of nonlinear optical response in the complexes formed from tetraalkylammonium halide and carbon tetrabromide is provided in view of electrostatic potentials of intermolecular donor (halide ion)-acceptor (CBr(4)). The calculated electrostatic potentials of donor-acceptor range from -4.83 to -7.70 kcal mol(-1) and show a decreasing order of [Et(4)Cl(-)Br] > [Et(4)Br(-)Br] congruent with [Et(4)I(-)Br] > [Bu(4)Br(-)Br]. The calculated second-order susceptibilities of solid complexes are in an increasing order of [NEt(4)ClCBr(4)] < [NEt(4)BrCBr(4)] congruent with [NEt(4)ICBr(4)] < [NBu(4)BrCBr(4)C(3)H(6)O]. It has been shown that the donor/acceptor dyads make the exclusive contribution to nonlinear optical response. A large size of halide or tetraalkylammonium ion results in a small electrostatic potential and large nonlinear optical response in these charge-transfer complexes. It indicates that a small supermolecular interaction will create a large nonlinear optical response, and it gives a clue to design the molecular complexes with large non-linear optical susceptibility.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Sep
pubmed:issn
0947-6539
pubmed:author
pubmed:issnType
Print
pubmed:day
6
pubmed:volume
12
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
6880-7
pubmed:dateRevised
2009-8-4
pubmed:meshHeading
pubmed:year
2006
pubmed:articleTitle
Electronic origin for enhanced nonlinear optical response of complexes from tetraalkylammonium halide and carbon tetrabromide: electrostatic potentials of intermolecular donor-acceptor dyads.
pubmed:affiliation
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, P.R. China.
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't