Source:http://linkedlifedata.com/resource/pubmed/id/16755622
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
23
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pubmed:dateCreated |
2006-8-25
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pubmed:abstractText |
Crystal frameworks that can accommodate a wide range of elements, oxidation states, and stoichiometries are an important component of solid-state chemistry. These frameworks allow for unique comparisons of different metal-cation compositions with identical atomic arrangements. The mineral Lyonsite, alpha-Cu(3)Fe(4)(VO(4))(6), is emerging as the archetypal framework structure for a large class of materials, similar to known frameworks such as perovskite, garnet, apatite, and spinel. The new lyonsite-type oxides Li(2.82)Hf(0.795)Mo(3)O(12) and Li(3.35)Ta(0.53)Mo(3)O(12), in which hafnium and tantalum retain their highest oxidation states, are presented to advance the concept of the lyonsite structure as an adaptable framework.
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pubmed:language |
eng
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pubmed:journal | |
pubmed:status |
PubMed-not-MEDLINE
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pubmed:month |
Aug
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pubmed:issn |
0947-6539
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pubmed:author | |
pubmed:issnType |
Print
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pubmed:day |
7
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pubmed:volume |
12
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
5944-53
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pubmed:dateRevised |
2009-8-4
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pubmed:year |
2006
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pubmed:articleTitle |
The adaptable lyonsite structure.
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pubmed:affiliation |
Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208-3113, USA.
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pubmed:publicationType |
Journal Article
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