Source:http://linkedlifedata.com/resource/pubmed/id/16749818
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Predicate | Object |
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
12
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pubmed:dateCreated |
2006-6-5
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pubmed:abstractText |
A novel one-dimensional coordination polymer made up of Fe(II), 3-cyanopyridine (3CNpy), and the singular in situ formed [Cu(I)(3CNpy)(CN)2]- anionic bridge has been synthesized. This compound undergoes a spin-crossover behavior according to its magnetic and calorimetric properties. The crystal structure of the title compound has been studied in the high- and low-spin states and correlated with the character of the spin conversion. Evidence for intense spin-state-dependent Cu....Cu interactions between the chains is also reported.
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pubmed:language |
eng
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pubmed:journal | |
pubmed:status |
PubMed-not-MEDLINE
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pubmed:month |
Jun
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pubmed:issn |
0020-1669
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pubmed:author | |
pubmed:issnType |
Print
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pubmed:day |
12
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pubmed:volume |
45
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
4583-5
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pubmed:year |
2006
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pubmed:articleTitle |
{Fe(3CNpy)2[Cu(3CNpy)(mu-CN)2]2}: a one-dimensional cyanide-based spin-crossover coordination polymer.
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pubmed:affiliation |
Departament de Física Aplicada, Universitat Politècnica de València, Camino de Vera s/n, 46022 València, Spain.
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pubmed:publicationType |
Journal Article
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