Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
12
pubmed:dateCreated
2006-6-5
pubmed:abstractText
A novel one-dimensional coordination polymer made up of Fe(II), 3-cyanopyridine (3CNpy), and the singular in situ formed [Cu(I)(3CNpy)(CN)2]- anionic bridge has been synthesized. This compound undergoes a spin-crossover behavior according to its magnetic and calorimetric properties. The crystal structure of the title compound has been studied in the high- and low-spin states and correlated with the character of the spin conversion. Evidence for intense spin-state-dependent Cu....Cu interactions between the chains is also reported.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Jun
pubmed:issn
0020-1669
pubmed:author
pubmed:issnType
Print
pubmed:day
12
pubmed:volume
45
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
4583-5
pubmed:year
2006
pubmed:articleTitle
{Fe(3CNpy)2[Cu(3CNpy)(mu-CN)2]2}: a one-dimensional cyanide-based spin-crossover coordination polymer.
pubmed:affiliation
Departament de Física Aplicada, Universitat Politècnica de València, Camino de Vera s/n, 46022 València, Spain.
pubmed:publicationType
Journal Article