Source:http://linkedlifedata.com/resource/pubmed/id/16737328
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
12
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pubmed:dateCreated |
2006-6-1
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pubmed:abstractText |
New molecular rotors, [7.7](2,6)pyridinocyclophanes (monomers and dimers) embedding 1,3-dioxanes in the bridges, were investigated by variable-temperature NMR, molecular modeling, and single-crystal X-ray diffractometry. The nitrogen-inside rotation of the pyridine ring is more hindered in the derivatives with longer distance between the bridges (i.e., para > meta and 2,6-pyridylene > ortho) and can be chemically stopped by complexation with CF(3)SO(3)Ag. [structure: see text]
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pubmed:language |
eng
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pubmed:journal | |
pubmed:status |
PubMed-not-MEDLINE
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pubmed:month |
Jun
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pubmed:issn |
1523-7060
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pubmed:author | |
pubmed:issnType |
Print
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pubmed:day |
8
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pubmed:volume |
8
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
2619-22
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pubmed:year |
2006
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pubmed:articleTitle |
Molecular rotors: design, synthesis, structural analysis, and silver complex of new [7.7]cyclophanes.
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pubmed:affiliation |
Babes-Bolyai University, Faculty of Chemistry and Chemical Engineering, 11 Arany Janos str., 400028 Cluj-Napoca, Romania.
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pubmed:publicationType |
Journal Article
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