Source:http://linkedlifedata.com/resource/pubmed/id/16719444
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
21
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| pubmed:dateCreated |
2006-5-24
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| pubmed:abstractText |
Reactions of bis(2,2'-biphenylylene)sulfuranyl bis(tetrafluoroborate) [(8-S-4(C4)]2+ with organo-lithium reagents (PhLi and MeLi) gave bis(2,2'-biphenylylene)di-C-substituted persulfuranes as a first persulfurane [12-S-6(C6)] having only carbon ligands. These compounds have been characterized by 1H and 13C NMR and mass spectroscopies. The structure of the dimethyl derivative was determined by X-ray crystallographic analysis, revealing that it has a distorted octahedral geometry with the two methyl ligands cis to each other, and subsequently, it was analyzed by an ab initio calculation.
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:month |
May
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| pubmed:issn |
0002-7863
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| pubmed:author | |
| pubmed:issnType |
Print
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| pubmed:day |
31
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| pubmed:volume |
128
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| pubmed:owner |
NLM
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| pubmed:authorsComplete |
Y
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| pubmed:pagination |
6778-9
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| pubmed:dateRevised |
2008-1-17
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| pubmed:year |
2006
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| pubmed:articleTitle |
Isolation and molecular structure of the organo-persulfuranes [12-S-6(C6)].
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| pubmed:affiliation |
Department of Chemistry, University of Tsukuba, Tsukuba, Ibaraki 305-8571, Japan. sato@chem.tsukuba.ac.jp
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| pubmed:publicationType |
Journal Article
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