Source:http://linkedlifedata.com/resource/pubmed/id/16673040
Switch to
Predicate | Object |
---|---|
rdf:type | |
lifeskim:mentions | |
pubmed:issue |
18
|
pubmed:dateCreated |
2006-5-4
|
pubmed:abstractText |
New heterofunctional phosphine ligands have been synthesised, incorporating the substitutionally labile sulfone and sulfonamide moieties as chelating groups, which display activity in the palladium-catalysed Suzuki and amination cross-coupling reactions. Single-crystal X-ray diffraction studies of the complexes formed with [Pd(mu-Cl)(dmba)] (dmba-H = N,N-dimethylbenzylamine) highlight the coordinating nature of these ligands; showing the formation of a bis chelate complex through a six-membered Pd-P-C-C-S-O ring with the sulfonamide class of ligands.
|
pubmed:language |
eng
|
pubmed:journal | |
pubmed:status |
PubMed-not-MEDLINE
|
pubmed:month |
May
|
pubmed:issn |
1477-9226
|
pubmed:author | |
pubmed:issnType |
Print
|
pubmed:day |
14
|
pubmed:owner |
NLM
|
pubmed:authorsComplete |
Y
|
pubmed:pagination |
2251-62
|
pubmed:year |
2006
|
pubmed:articleTitle |
Structure and reactivity of new phosphine ligands containing the hemi-labile sulfone moiety.
|
pubmed:affiliation |
Department of Chemistry, University of Bath, Claverton down, Bath, UK BA2 7AY.
|
pubmed:publicationType |
Journal Article
|