Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
18
pubmed:dateCreated
2006-5-4
pubmed:abstractText
New heterofunctional phosphine ligands have been synthesised, incorporating the substitutionally labile sulfone and sulfonamide moieties as chelating groups, which display activity in the palladium-catalysed Suzuki and amination cross-coupling reactions. Single-crystal X-ray diffraction studies of the complexes formed with [Pd(mu-Cl)(dmba)] (dmba-H = N,N-dimethylbenzylamine) highlight the coordinating nature of these ligands; showing the formation of a bis chelate complex through a six-membered Pd-P-C-C-S-O ring with the sulfonamide class of ligands.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
May
pubmed:issn
1477-9226
pubmed:author
pubmed:issnType
Print
pubmed:day
14
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
2251-62
pubmed:year
2006
pubmed:articleTitle
Structure and reactivity of new phosphine ligands containing the hemi-labile sulfone moiety.
pubmed:affiliation
Department of Chemistry, University of Bath, Claverton down, Bath, UK BA2 7AY.
pubmed:publicationType
Journal Article