Source:http://linkedlifedata.com/resource/pubmed/id/16643041
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Predicate | Object |
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
4
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pubmed:dateCreated |
2006-4-28
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pubmed:abstractText |
A new 12-membered macrolide (chloriolide; 1) was obtained from solid-substrate fermentation cultures of Chloridium virescens var. chlamydosporum that was originally isolated from decayed wood. The structure of 1 was determined by analysis of 1D NMR, 2D NMR, and MS data and confirmed by X-ray crystallographic analysis. The absolute configuration of 1 was assigned by application of the modified Mosher method using the (R)- and (S)-MTPA derivatives of a rearrangement product obtained under standard acylation conditions. The assignment made by analysis of the corresponding Deltadelta values was verified by X-ray crystallographic analysis of the (S)-MTPA derivative.
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pubmed:language |
eng
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pubmed:journal | |
pubmed:citationSubset |
IM
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pubmed:chemical | |
pubmed:status |
MEDLINE
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pubmed:month |
Apr
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pubmed:issn |
0163-3864
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pubmed:author | |
pubmed:issnType |
Print
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pubmed:volume |
69
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
636-9
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pubmed:dateRevised |
2006-11-15
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pubmed:meshHeading |
pubmed-meshheading:16643041-Ascomycota,
pubmed-meshheading:16643041-Crystallography, X-Ray,
pubmed-meshheading:16643041-Florida,
pubmed-meshheading:16643041-Macrolides,
pubmed-meshheading:16643041-Microbial Sensitivity Tests,
pubmed-meshheading:16643041-Molecular Conformation,
pubmed-meshheading:16643041-Molecular Structure,
pubmed-meshheading:16643041-Nuclear Magnetic Resonance, Biomolecular,
pubmed-meshheading:16643041-Stereoisomerism
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pubmed:year |
2006
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pubmed:articleTitle |
Chloriolide, a 12-membered macrolide from Chloridium virescens var. chlamydosporum (NRRL 37636).
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pubmed:affiliation |
Department of Chemistry, University of Iowa, Iowa City, IA 52242, USA.
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pubmed:publicationType |
Journal Article,
Research Support, U.S. Gov't, Non-P.H.S.
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