Linked Life Data

16568973

Source:http://linkedlifedata.com/resource/pubmed/id/16568973

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
13
pubmed:dateCreated
2006-3-29
pubmed:abstractText
We investigated methanol adsorption and dissociation on bridge-bonded oxygen vacancies of the TiO2(110)-(1x1) surface using in situ scanning tunneling microscopy. We provide the first direct evidence that methanol dissociates on oxygen vacancies via O-H bond scission rather than C-O scission. For CH3OH coverages lower than the oxygen vacancy concentration, stationary methoxy-hydroxyl pairs form. At CH3OH coverages close to the oxygen vacancy concentration undissociated mobile CH3OH interacts with methoxy-hydroxyl pairs and facilitates the movement of hydroxyl away from the methoxy group.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Apr
pubmed:issn
0002-7863
pubmed:author
pubmed:issnType
Print
pubmed:day
5
pubmed:volume
128
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
4198-9
pubmed:dateRevised
2008-1-17
pubmed:year
2006
pubmed:articleTitle
Imaging adsorbate O-H bond cleavage: methanol on TiO2(110).
pubmed:affiliation
Department of Chemistry and Biochemistry, Center for Materials Chemistry, University of Texas at Austin, 78712, USA.
pubmed:publicationType
Journal Article