Linked Life Data

16497036

Source:http://linkedlifedata.com/resource/pubmed/id/16497036

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
7
pubmed:dateCreated
2006-2-24
pubmed:abstractText
The collision-induced dissociation of VO(+) by Xe has been studied by the use of classical dynamics procedures on London-Eyring-Polanyi-Sato potential-energy surfaces in the collision energy range of 5.0-30 eV. The dissociation threshold behavior and the dependence of reaction cross sections on the collision energy closely follow the observed data with the threshold energy of 6.00 eV. The principal reaction pathway is VO(+) + Xe --> V(+)+ O + Xe and the minor pathway is VO(+) + Xe--> VXe(+) + O. At higher collision energies (E > 8.0 eV), the former reaction preferentially occurs near the O-V(+)...Xe collinear and perpendicular alignments, but the latter only occurs near the perpendicular alignment. At lower energies close to the threshold, the reactions are found to occur near the collinear configuration. No reaction occurs in the collinear alignment V(+)-O...Xe. The high and low energy-transfer efficiencies of the collinear alignments O-V(+)...Xe and V(+)-O...Xe are attributed to the effects of mass distribution. The activation of the VO(+) bond toward the dissociation threshold occurs through a translation-to-vibration energy transfer in a strong collision on a time scale of about 50 fs.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Feb
pubmed:issn
0021-9606
pubmed:author
pubmed:issnType
Print
pubmed:day
21
pubmed:volume
124
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
74307
pubmed:year
2006
pubmed:articleTitle
Collision-induced dissociation of transition metal-oxide ions: dynamics of VO+ collision with Xe.
pubmed:affiliation
Department of Chemistry Education, Chonnam National University, Kwangju, Korea.
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't