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PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
7
pubmed:dateCreated
2006-2-23
pubmed:abstractText
The statistical associating fluid theory of Wertheim is applied to describe binary mixtures with associating between unlike-pair molecules. The phase behavior of this binary mixture would fall into five different types (I, II, III, V, and VI) of the classification scheme of van Konynenburg and Scott by varying the associating strength and the energy parameters. Both interfacial wetting behavior and wetting transitions are carefully examined in all the vapor-liquid-liquid (gamma-beta-alpha) three-phase-coexisting regions of the binary mixtures. The global wetting behavior and wetting transitions are delineated by scanning the parameter space. In certain regions, the middle beta phase exhibits interfacial phase transitions sequentially, nonwetting --> partial-wetting --> nonwetting, at the interface separating lower alpha and upper gamma phases along with increasing temperature.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Feb
pubmed:issn
1520-6106
pubmed:author
pubmed:issnType
Print
pubmed:day
23
pubmed:volume
110
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
3294-301
pubmed:year
2006
pubmed:articleTitle
Bulk and interfacial wetting behavior of binary mixtures induced by associating between unlike-pair molecules.
pubmed:affiliation
Department of Chemical Engineering, National Taiwan University, Taipei, Taiwan 10617, Republic of China.
pubmed:publicationType
Journal Article