16478164

Source:http://linkedlifedata.com/resource/pubmed/id/16478164

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Predicate	Object
rdf:type	pubmed:Citation
lifeskim:mentions	umls-concept:C0001975, umls-concept:C0079411, umls-concept:C0457555, umls-concept:C1524063
pubmed:issue	7
pubmed:dateCreated	2006-2-15
pubmed:abstractText	Treatment of tertiary homoallyl alcohol with aryl halide under palladium catalysis resulted in the transfer of the allyl moiety of the homoallyl alcohol to aryl halide and yielded the corresponding cross-coupling product stereo- and regiospecifically. The transfer process includes retro-allylation, which proceeds via a conformationally regulated six-membered transition state. The retro-allylation can be regarded as a method for the stereo- and regiospecific preparation of sigma-allylpalladium.
pubmed:language	eng
pubmed:journal	http://linkedlifedata.com/resource/pubmed/journal/7503056
pubmed:status	PubMed-not-MEDLINE
pubmed:month	Feb
pubmed:issn	0002-7863
pubmed:author	pubmed-author:HayashiSayuriS, pubmed-author:HiranoKojiK, pubmed-author:OshimaKoichiroK, pubmed-author:YorimitsuHidekiH
pubmed:issnType	Print
pubmed:day	22
pubmed:volume	128
pubmed:owner	NLM
pubmed:authorsComplete	Y
pubmed:pagination	2210-1
pubmed:dateRevised	2008-1-17
pubmed:year	2006
pubmed:articleTitle	Palladium-catalyzed stereo- and regiospecific allylation of aryl halides with homoallyl alcohols via retro-allylation: selective generation and use of sigma-allylpalladium.
pubmed:affiliation	Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoto-daigaku Katsura, Nishikyo-ku, Kyoto 615-8510, Japan.
pubmed:publicationType	Journal Article