Source:http://linkedlifedata.com/resource/pubmed/id/16464108
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
6
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| pubmed:dateCreated |
2006-2-8
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| pubmed:abstractText |
Acid-assisted reductive elimination of hydrogen from Tp'PtH(3) and of methane and hydrogen from Tp'PtMeH(2) (Tp' = hydridotris(3,5-dimethylpyrazolyl)borate) is examined herein. Loss of H(2) is observed from solutions containing platinum(IV) complexes of the type Tp'Pt(R)(H)(2) (R = Me, H) upon protonation and addition of a ligand such as CO. Results of kinetic studies on reductive elimination of H(2) and formation of [kappa(2)-(HTp')Pt(R)(L)][BAr'(4)] products from intermediates derived from Tp'Pt(R)(H)(2) precursors are described. Elimination appears to occur from cationic 6-coordinate [kappa(2)-(HTp')Pt(R)(H)(2)(L)][BAr'(4)] species.
|
| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
|
| pubmed:month |
Feb
|
| pubmed:issn |
0002-7863
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| pubmed:author | |
| pubmed:issnType |
Print
|
| pubmed:day |
15
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| pubmed:volume |
128
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| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
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| pubmed:pagination |
2059-66
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| pubmed:year |
2006
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| pubmed:articleTitle |
Carbon monoxide promoted reductive elimination of hydrogen from Tp' platinum complexes.
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| pubmed:affiliation |
Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, NC 27599-3290, USA.
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| pubmed:publicationType |
Journal Article
|