16438048

Source:http://linkedlifedata.com/resource/pubmed/id/16438048

Download in:

Switch to

Custom View

Named Graph Language Inference

Statements in which the resource exists as a subject.
Predicate	Object
rdf:type	pubmed:Citation
lifeskim:mentions	umls-concept:C0028621, umls-concept:C0028630, umls-concept:C0220781, umls-concept:C1709634, umls-concept:C1883254
pubmed:issue	10-12
pubmed:dateCreated	2006-1-27
pubmed:abstractText	The synthesis of 2'-C-methyl-4'-thiocytidine (16) is described. Since the 2'-keto-4'-thiocytidine derivative 2beta unexpectedly isomerized to 2alpha and the methylation of 2beta proceeded predominantly from the less hindered alpha-face to give 7, the desired product 16 was synthesized via the Pummerer reaction of the sulfoxide 14 and N4-benzoylcytosine.
pubmed:language	eng
pubmed:journal	http://linkedlifedata.com/resource/pubmed/journal/100892832
pubmed:citationSubset	IM
pubmed:chemical	http://linkedlifedata.com/resource/pubmed/chemical/Cytidine
pubmed:status	MEDLINE
pubmed:issn	1525-7770
pubmed:author	pubmed-author:KagaDaisukeD, pubmed-author:MatsudaAkiraA, pubmed-author:MinakawaNoriakiN
pubmed:issnType	Print
pubmed:volume	24
pubmed:owner	NLM
pubmed:authorsComplete	Y
pubmed:pagination	1789-800
pubmed:dateRevised	2006-11-15
pubmed:meshHeading	pubmed-meshheading:16438048-Cytidine
pubmed:year	2005
pubmed:articleTitle	Nucleosides and nucleotides. 232. Synthesis of 2'-C-methyl-4'-thiocytidine: unexpected anomerization of the 2'-keto-4'-thionucleoside precursor.
pubmed:affiliation	Graduate School of Pharmaceutical Sciences, Hokkaido University, Kita-ku, Sapporo, Japan.
pubmed:publicationType	Journal Article, Research Support, Non-U.S. Gov't