16408878

Source:http://linkedlifedata.com/resource/pubmed/id/16408878

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Predicate	Object
rdf:type	pubmed:Citation
lifeskim:mentions	umls-concept:C0060264, umls-concept:C0599225, umls-concept:C1257890
pubmed:issue	2
pubmed:dateCreated	2006-1-13
pubmed:abstractText	[reaction: see text] Ortho-lithiation of (2R,4S,5R)-3,4-dimethyl-2-ferrocenyl-5-phenyl[1,3,2]oxazaphospholidine 2-oxide 2 was carried out with diastereoselectivity of >99%, affording a new and efficient way for introducing planar chirality into the ferrocene backbone. Various electrophiles were used to quench the lithiated species, showing the wide applicability of the new ortho-directing group and its potential to generate ligands for use in asymmetric catalysis.
pubmed:language	eng
pubmed:journal	http://linkedlifedata.com/resource/pubmed/journal/100890393
pubmed:status	PubMed-not-MEDLINE
pubmed:month	Jan
pubmed:issn	1523-7060
pubmed:author	pubmed-author:HancockFredF, pubmed-author:MateusNunoN, pubmed-author:SteinerAlexanderA, pubmed-author:VinciDanieleD, pubmed-author:WuXiaofengX, pubmed-author:XiaoJianliangJ
pubmed:issnType	Print
pubmed:day	19
pubmed:volume	8
pubmed:owner	NLM
pubmed:authorsComplete	Y
pubmed:pagination	215-8
pubmed:year	2006
pubmed:articleTitle	Oxazaphospholidine-oxide as an efficient ortho-directing group for the diastereoselective deprotonation of ferrocene.
pubmed:affiliation	Department of Chemistry, University of Liverpool, UK.
pubmed:publicationType	Journal Article