|
rdf:type |
|
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lifeskim:mentions |
umls-concept:C0007447,
umls-concept:C0022071,
umls-concept:C0025552,
umls-concept:C0031694,
umls-concept:C0183210,
umls-concept:C0185125,
umls-concept:C0205250,
umls-concept:C0220781,
umls-concept:C0332324,
umls-concept:C0439855,
umls-concept:C1707689,
umls-concept:C1883254
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pubmed:issue |
1
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pubmed:dateCreated |
2005-12-16
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|
pubmed:abstractText |
A new metal cation probe bearing a central Ir(III) element and 1-aza-15-crown-5-ether substituted pyridyl pyrazolate as the chelate was synthesized. The octahedral molecular structure of was confirmed using single crystal X-ray diffraction analyses. Subsequent photophysical study showed yellow-green emission at approximately 560 nm in both fluid solution and solid state at room temperature. Remarkable differentiation in spectral properties upon metal cation (e.g. Ca2+) complexation makes complex a highly sensitive phosphorescence probe.
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pubmed:language |
eng
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pubmed:journal |
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pubmed:citationSubset |
IM
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pubmed:chemical |
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pubmed:status |
MEDLINE
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pubmed:month |
Jan
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pubmed:issn |
1477-0520
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pubmed:author |
|
|
pubmed:issnType |
Print
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pubmed:day |
7
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pubmed:volume |
4
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
|
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pubmed:pagination |
98-103
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pubmed:meshHeading |
|
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pubmed:year |
2006
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pubmed:articleTitle |
Design and synthesis of iridium(III) azacrown complex: application as a highly sensitive metal cation phosphorescence sensor.
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pubmed:affiliation |
Department of Chemistry, National Taiwan University, Taipei, 106, Taiwan.
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pubmed:publicationType |
Journal Article,
Research Support, Non-U.S. Gov't
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