Source:http://linkedlifedata.com/resource/pubmed/id/16272588
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
Pt 11
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| pubmed:dateCreated |
2005-11-7
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| pubmed:abstractText |
Reaction of 3-(4-pyridyl)pyrazole (4pypz) with cobalt(II) chloride in acetonitrile affords the title complex, [CoCl(2)(C(8)H(7)N(3))(4)].4CH(3)CN, within seconds of addition, as purple X-ray quality crystals. The molecule has C4 symmetry. The metal ion exhibits a trans-N(4)Cl(2) octahedral geometry, with the four 3-(4-pyridyl)-1H-pyrazole ligands coordinating through their pyridyl N-atom donors; one coordinated chloride ion forms hydrogen bonds with the pyrazole rings from four separate units. This configuration creates an infinite three-dimensional coordination network containing channels that are filled with acetonitrile solvent molecules.
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
|
| pubmed:month |
Nov
|
| pubmed:issn |
0108-2701
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| pubmed:author | |
| pubmed:issnType |
Print
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| pubmed:volume |
61
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| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
|
| pubmed:pagination |
m485-7
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| pubmed:year |
2005
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| pubmed:articleTitle |
Dichlorotetrakis[3-(4-pyridyl)-1H-pyrazole]cobalt(II) acetonitrile tetrasolvate: an infinite hydrogen-bonded network, in an instant.
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| pubmed:affiliation |
Department of Chemistry, University of Sheffield, Sheffield S3 7HF, England.
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| pubmed:publicationType |
Journal Article
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