Linked Life Data

16248605

Source:http://linkedlifedata.com/resource/pubmed/id/16248605

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
43
pubmed:dateCreated
2005-10-26
pubmed:abstractText
A new heteroditopic receptor for alkali metal halides has been designed and synthesized. It is comprised of a well-established motif for cation binding and a motif for halogen-bonding-based anion recognition processes. The single-crystal X-ray structure of the complex between the heteroditopic receptor and sodium iodide is reported. Thanks to the cooperativity of metal coordination and the strong I-...I halogen bonding, the ion pair is fully separated. The boosting effect of the binding of the anion through halogen bonding on the coordination of the cation by the receptor has been proved also in solution by NMR experiments. The selectivity of the new heterotopic receptor toward different alkali metal halides has been tested by ESI mass experiments.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Nov
pubmed:issn
0002-7863
pubmed:author
pubmed:issnType
Print
pubmed:day
2
pubmed:volume
127
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
14972-3
pubmed:dateRevised
2008-1-17
pubmed:year
2005
pubmed:articleTitle
A halogen-bonding-based heteroditopic receptor for alkali metal halides.
pubmed:affiliation
NFMLab-DCMIC G. Natta and Polo di Como, Politecnico di Milano, Via L. Mancinelli 7, 20131 Milan, Italy.
pubmed:publicationType
Journal Article