16235931

Source:http://linkedlifedata.com/resource/pubmed/id/16235931

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Predicate	Object
rdf:type	pubmed:Citation
lifeskim:mentions	umls-concept:C0002078, umls-concept:C0007009, umls-concept:C0007382, umls-concept:C0205099, umls-concept:C0441513, umls-concept:C0598128, umls-concept:C1527177
pubmed:issue	22
pubmed:dateCreated	2005-10-20
pubmed:abstractText	[reaction: see text] The enantioselective [2 + 2 + 2] cycloaddition of 1,6-enynes and alkynes using chiral rhodium catalysts gave cycloadducts containing quaternary carbon stereocenters. Both symmetrical and unsymmetrical alkynes and acetylene could be used as coupling partners, and the corresponding bicyclic cyclohexa-1,3-dienes were obtained in good to excellent ee.
pubmed:language	eng
pubmed:journal	http://linkedlifedata.com/resource/pubmed/journal/100890393
pubmed:status	PubMed-not-MEDLINE
pubmed:month	Oct
pubmed:issn	1523-7060
pubmed:author	pubmed-author:AraiYoshikazuY, pubmed-author:ShibataTakanoriT, pubmed-author:TaharaYu-KiYK
pubmed:issnType	Print
pubmed:day	27
pubmed:volume	7
pubmed:owner	NLM
pubmed:authorsComplete	Y
pubmed:pagination	4955-7
pubmed:year	2005
pubmed:articleTitle	Enantioselective construction of quaternary carbon centers by catalytic [2 + 2 + 2] cycloaddition of 1,6-enynes and alkynes.
pubmed:affiliation	Department of Chemistry, School of Science and Engineering, Waseda University, Shinjuku, Tokyo, Japan. tshibata@waseda.jp
pubmed:publicationType	Journal Article