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PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
21
pubmed:dateCreated
2005-10-10
pubmed:abstractText
1H, 31P, and 7Li pulsed-gradient spin-echo (PGSE) diffusion and variable-temperature NMR results for THF solutions of the lithium and potassium salts derived from diphenylphosphino(o-cyanophenyl)aniline are reported and compared to the solid-state results obtained via X-ray diffraction studies. The solution results favor mononuclear salts, sometimes strongly ion paired, whereas the solid-state data reveal dinuclear species. The structures of the products from reactions of these salts with crown ethers are determined via PGSE and 1H Overhauser NMR methods.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Oct
pubmed:issn
0020-1669
pubmed:author
pubmed:issnType
Print
pubmed:day
17
pubmed:volume
44
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
7616-23
pubmed:year
2005
pubmed:articleTitle
NMR, PGSE diffusion, and X-ray diffraction studies of lithium and potassium salts derived from diphenylphosphino(o-cyanophenyl)aniline and their crown ether complexes.
pubmed:affiliation
Laboratory of Inorganic Chemistry, ETHZ, Hönggerberg, CH-8093 Zürich, Switzerland.
pubmed:publicationType
Journal Article