Source:http://linkedlifedata.com/resource/pubmed/id/16212388
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
21
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pubmed:dateCreated |
2005-10-10
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pubmed:abstractText |
1H, 31P, and 7Li pulsed-gradient spin-echo (PGSE) diffusion and variable-temperature NMR results for THF solutions of the lithium and potassium salts derived from diphenylphosphino(o-cyanophenyl)aniline are reported and compared to the solid-state results obtained via X-ray diffraction studies. The solution results favor mononuclear salts, sometimes strongly ion paired, whereas the solid-state data reveal dinuclear species. The structures of the products from reactions of these salts with crown ethers are determined via PGSE and 1H Overhauser NMR methods.
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pubmed:language |
eng
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pubmed:journal | |
pubmed:status |
PubMed-not-MEDLINE
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pubmed:month |
Oct
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pubmed:issn |
0020-1669
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pubmed:author | |
pubmed:issnType |
Print
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pubmed:day |
17
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pubmed:volume |
44
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
7616-23
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pubmed:year |
2005
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pubmed:articleTitle |
NMR, PGSE diffusion, and X-ray diffraction studies of lithium and potassium salts derived from diphenylphosphino(o-cyanophenyl)aniline and their crown ether complexes.
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pubmed:affiliation |
Laboratory of Inorganic Chemistry, ETHZ, Hönggerberg, CH-8093 Zürich, Switzerland.
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pubmed:publicationType |
Journal Article
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