Linked Life Data

16212168

Source:http://linkedlifedata.com/resource/pubmed/id/16212168

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
4
pubmed:dateCreated
2005-10-10
pubmed:abstractText
Direct electrochemical behaviors of hemoglobin (Hb) immobilized on carbon nanotube (CNT) modified carbon paste electrode with adsorption were investigated. Cyclic voltammetry of Hb-CNT-modified electrode showed a pair of well-defined and nearly reversible peaks for HbhemeFe(III) /Fe(II) redox couple in pH = 7 PBS buffers. The electrocatalytic behaviors of Hb-CNT-modified electrode for the reductive dechlorination of trichloroacetic acid (TCA) were studied by cyclic voltammmetry and fixed-potential electrolysis technique, and the reductive mechanism of TCA was discussed by analysis of reduction products. The results showed that Hb-CNT-modified electrode possessed good electro-catalytic activity for reduction of TCA and the dechlorination of TCA was stepwise, following the pathway of trichloroacetic--> dichloroacetic--> monochloroacetic--> acetic. The dechlorination of TCA in waster water was investigated using a two-compartment flow reactor with working electrode compartment packed with Hb-CNT-modified graphite electrode. The conversion of TCA was 40.13% with electrolysis for 180 min at - 0.60V (vs. SCE).
pubmed:language
chi
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Jul
pubmed:issn
0250-3301
pubmed:author
pubmed:issnType
Print
pubmed:volume
26
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
55-8
pubmed:meshHeading
pubmed:year
2005
pubmed:articleTitle
[Reductive dechlorination of trichloroacetic acid by bioelectrochemically catalytic method].
pubmed:affiliation
Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100080, China.
pubmed:publicationType
Journal Article, English Abstract, Research Support, Non-U.S. Gov't