Linked Life Data

16206299

Source:http://linkedlifedata.com/resource/pubmed/id/16206299

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
3
pubmed:dateCreated
2006-1-18
pubmed:abstractText
Herein, we report the synthesis of a molecular clip with TTF side-walls and its binding behavior towards electron-deficient guests, namely the formation of macrocycle/molecular-clip supramolecular complexes in solution. Four different sets of external stimuli--the K(+)/[2.2.2]cryptand, NH(4) (+)/Et(3)N and (p-BrPh)(3)NSbCl(6)/Zn pairs, and heating/cooling cycles-control the movement of this molecular switch between its threaded and unthreaded states and provide color changes that are observable by the naked eye. This macrocycle/molecular-clip complex system can be considered not only as a quadruple-use molecular switch, but can also be operated by three of these stimuli as a three-input molecular NOR-functioning logic gate that may be monitored by UV-visible spectroscopy.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Jan
pubmed:issn
0947-6539
pubmed:author
pubmed:issnType
Print
pubmed:day
11
pubmed:volume
12
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
865-76
pubmed:dateRevised
2009-8-4
pubmed:meshHeading
pubmed:year
2006
pubmed:articleTitle
A macrocycle/molecular-clip complex that functions as a quadruply controllable molecular switch.
pubmed:affiliation
Department of Chemistry, National Taiwan University, Taipei, ROC.
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't