Source:http://linkedlifedata.com/resource/pubmed/id/16173739
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Predicate | Object |
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
38
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pubmed:dateCreated |
2005-9-21
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pubmed:abstractText |
A triptycene-based homotritopic host was designed and synthesized. Assembly of the host with a bisbenzylammonium salt containing terminal double bonds resulted in a tris[2]pseudorotaxane, which further performed the threefold metathesis reaction and then hydrogenation to give a [4]pseudocatenane in high yield. The [4]pseudocatenane exhibited a novel topological structure with high symmetry, which was confirmed by the spectral data and X-ray analysis.
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pubmed:language |
eng
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pubmed:journal | |
pubmed:citationSubset |
IM
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pubmed:chemical | |
pubmed:status |
MEDLINE
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pubmed:month |
Sep
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pubmed:issn |
0002-7863
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pubmed:author | |
pubmed:issnType |
Print
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pubmed:day |
28
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pubmed:volume |
127
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
13158-9
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pubmed:dateRevised |
2008-1-17
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pubmed:meshHeading | |
pubmed:year |
2005
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pubmed:articleTitle |
A highly efficient approach to [4]pseudocatenanes by threefold metathesis reactions of a triptycene-based tris[2]pseudorotaxane.
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pubmed:affiliation |
Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China.
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pubmed:publicationType |
Journal Article,
Research Support, Non-U.S. Gov't
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