16149786

Source:http://linkedlifedata.com/resource/pubmed/id/16149786

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Predicate	Object
rdf:type	pubmed:Citation
lifeskim:mentions	umls-concept:C0030230, umls-concept:C0175921, umls-concept:C0332120, umls-concept:C0439851, umls-concept:C0443286, umls-concept:C1552596, umls-concept:C1749467, umls-concept:C1947931
pubmed:issue	19
pubmed:dateCreated	2005-9-9
pubmed:abstractText	[reactions: see text] Palladium hydroxide on carbon (Pearlman's catalyst) effectively catalyzes direct arylation reactions of aryl iodides and bromides, providing excellent arylation-to-hydrodehalogenation ratios (>30:1) with broad scope for both intra- and intermolecular arylation processes. Studies aimed at determining the nature of the active catalyst indicate that an active homogeneous palladium species is produced under the reaction conditions.
pubmed:language	eng
pubmed:journal	http://linkedlifedata.com/resource/pubmed/journal/2985193R
pubmed:status	PubMed-not-MEDLINE
pubmed:month	Sep
pubmed:issn	0022-3263
pubmed:author	pubmed-author:FagnouKeithK, pubmed-author:ParisienMathieuM, pubmed-author:ValetteDamienD
pubmed:issnType	Print
pubmed:day	16
pubmed:volume	70
pubmed:owner	NLM
pubmed:authorsComplete	Y
pubmed:pagination	7578-84
pubmed:year	2005
pubmed:articleTitle	Direct arylation reactions catalyzed by Pd(OH)2/C: evidence for a soluble palladium catalyst.
pubmed:affiliation	Center for Catalysis Research and Innovation, Department of Chemistry, University of Ottawa, 10 Marie Curie, Ottawa, Ontario, Canada K1N 6N5.
pubmed:publicationType	Journal Article