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Predicate | Object |
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
3
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pubmed:dateCreated |
1992-7-24
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pubmed:abstractText |
We have studied the surface chemistry of two lots of Biomer (BSP067 and BSUA001), a widely used commercial poly(ether urethane) (PEU). Although transmission infrared adsorption studies revealed no differences in the bulk chemistry of the two lots, the surface chemistry, as seen by x-ray photoelectron spectroscopy (XPS) and static secondary ion mass spectrometry (SIMS), was different. Lot BSP067 showed soft-segment enrichment at the surface, which is typical of PEU. Lot BSUA001 showed no evidence of either hard- or soft-segment PEU components at the surface. The surface of this lot was completely covered with a nonextractable additive identified as poly(diisopropyl amino ethyl methacrylate). Small amounts of a low-molecular-weight antioxidant were observed at the surface of both samples. Because the biological response to polymers is dependent on surface structure, these results are of considerable importance to biomaterials research.
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pubmed:grant | |
pubmed:language |
eng
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pubmed:journal | |
pubmed:citationSubset |
IM
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pubmed:chemical | |
pubmed:status |
MEDLINE
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pubmed:month |
Mar
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pubmed:issn |
0021-9304
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pubmed:author | |
pubmed:issnType |
Print
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pubmed:volume |
26
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
273-89
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pubmed:dateRevised |
2007-11-14
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pubmed:meshHeading |
pubmed-meshheading:1613021-Antioxidants,
pubmed-meshheading:1613021-Biocompatible Materials,
pubmed-meshheading:1613021-Chromatography, Gel,
pubmed-meshheading:1613021-Electron Probe Microanalysis,
pubmed-meshheading:1613021-Molecular Structure,
pubmed-meshheading:1613021-Polyurethanes,
pubmed-meshheading:1613021-Spectrophotometry, Infrared,
pubmed-meshheading:1613021-Surface Properties
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pubmed:year |
1992
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pubmed:articleTitle |
Variations between Biomer lots. I. Significant differences in the surface chemistry of two lots of a commercial poly(ether urethane).
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pubmed:affiliation |
Department of Chemical Engineering, University of Washington, Seattle 98195.
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pubmed:publicationType |
Journal Article,
Comparative Study,
Research Support, U.S. Gov't, P.H.S.
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