16127490

Source:http://linkedlifedata.com/resource/pubmed/id/16127490

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Predicate	Object
rdf:type	pubmed:Citation
lifeskim:mentions	umls-concept:C0002068, umls-concept:C0007382, umls-concept:C0682906, umls-concept:C1527178, umls-concept:C1705938, umls-concept:C2003941
pubmed:issue	18
pubmed:dateCreated	2005-8-29
pubmed:abstractText	An alpha,beta-(C-C-C) agostic bond is found to provide the additional stabilization needed to make the formally 14-electron metallacyclobutane intermediate lower in energy than its 16-electron alkylidene analogue during olefin metathesis catalysis.
pubmed:language	eng
pubmed:journal	http://linkedlifedata.com/resource/pubmed/journal/101176026
pubmed:citationSubset	IM
pubmed:chemical	http://linkedlifedata.com/resource/pubmed/chemical/Alkenes, http://linkedlifedata.com/resource/pubmed/chemical/Organometallic Compounds, http://linkedlifedata.com/resource/pubmed/chemical/Transition Elements
pubmed:status	MEDLINE
pubmed:month	Sep
pubmed:issn	1477-9226
pubmed:author	pubmed-author:BaikMu-HyunMH, pubmed-author:SureshCherumuttathu HCH
pubmed:issnType	Print
pubmed:day	21
pubmed:owner	NLM
pubmed:authorsComplete	Y
pubmed:pagination	2982-4
pubmed:meshHeading	pubmed-meshheading:16127490-Alkenes, pubmed-meshheading:16127490-Catalysis, pubmed-meshheading:16127490-Models, Chemical, pubmed-meshheading:16127490-Molecular Conformation, pubmed-meshheading:16127490-Organometallic Compounds, pubmed-meshheading:16127490-Transition Elements
pubmed:year	2005
pubmed:articleTitle	Alpha,beta-(C-C-C) agostic bonds in transition metal based olefin metathesis catalyses.
pubmed:affiliation	Department of Chemistry and School of Informatics, Indiana University, Bloomington, Indiana 47405, USA.
pubmed:publicationType	Journal Article, Research Support, Non-U.S. Gov't