Source:http://linkedlifedata.com/resource/pubmed/id/16075112
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Predicate | Object |
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
16
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pubmed:dateCreated |
2005-8-2
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pubmed:abstractText |
New mixed metal clusters with M19 metal frameworks have been synthesized by NaBH4 reduction of Au(NO3)(PMe2Ph) together with AgNO3 in ethanol. Single crystal X-ray diffraction has revealed Au12Ag7 and Au17Ag2 metal skeletons for these clusters, which are best described in terms of bicapped pentagonal antiprismatic cages with a staggered-staggered M(5) ring configuration. These clusters connect the missing link between M13 icosahedral and M25 biicosahedral clusters providing a view of the cluster growth process. A TEM image of this cluster has been observed, which has clearly demonstrated single-sized nano-particles of less than 1.0 nm.
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pubmed:language |
eng
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pubmed:journal | |
pubmed:citationSubset |
IM
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pubmed:chemical | |
pubmed:status |
MEDLINE
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pubmed:month |
Aug
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pubmed:issn |
1477-9226
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pubmed:author |
pubmed-author:ChibaHirokazuH,
pubmed-author:FunahashiYasuhiroY,
pubmed-author:ItoMitsuhiroM,
pubmed-author:MasudaHidekiH,
pubmed-author:NakamotoMasamiM,
pubmed-author:NishiharaHiroshiH,
pubmed-author:NunokawaKeikoK,
pubmed-author:OnakaSatoruS,
pubmed-author:OzekiTomojiT,
pubmed-author:SunaharaTetsuyaT,
pubmed-author:YamamotoMariM,
pubmed-author:YonezawaTetsuT
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pubmed:issnType |
Print
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pubmed:day |
21
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
2726-30
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pubmed:meshHeading |
pubmed-meshheading:16075112-Crystallography, X-Ray,
pubmed-meshheading:16075112-Gold,
pubmed-meshheading:16075112-Microscopy, Electron, Transmission,
pubmed-meshheading:16075112-Models, Molecular,
pubmed-meshheading:16075112-Organometallic Compounds,
pubmed-meshheading:16075112-Sensitivity and Specificity,
pubmed-meshheading:16075112-Silver,
pubmed-meshheading:16075112-Spectrophotometry,
pubmed-meshheading:16075112-X-Rays
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pubmed:year |
2005
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pubmed:articleTitle |
A new 19-metal-atom cluster [(Me2PhP)10Au12Ag7(NO3)9] with a nearly staggered-staggered M5 ring configuration.
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pubmed:affiliation |
Department of Environmental Technology, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466-8555, Japan.
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pubmed:publicationType |
Journal Article,
Research Support, Non-U.S. Gov't
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