Source:http://linkedlifedata.com/resource/pubmed/id/16050684
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
16
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| pubmed:dateCreated |
2005-7-29
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| pubmed:abstractText |
Syntheses of the first bis-calixarenes systems bridged by a tetrathiafulvalene (TTF) framework 5a,b have been carried out in good yields through triethyl phosphite-mediated dechalcogenation-dimerizations of the corresponding 1,3-dithiole-2-(thi)ones 3 or 4. X-ray structures of the calix[4]arene-TTF-calix[4]arene assembly 5b and of the calix[4]arene-thione intermediate 3b are analyzed and confirm the cone conformations adopted by the calix[4]arene parts, as it is also observed by (1)H NMR analysis of these systems. The solid-state organization in 5b leads to alternate layers of calixarene and TTF units. The cyclic voltammograms of 5a,b show as expected a two-step redox behavior but display a CV deformation for the second redox process.
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:month |
Aug
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| pubmed:issn |
0022-3263
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| pubmed:author | |
| pubmed:issnType |
Print
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| pubmed:day |
5
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| pubmed:volume |
70
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| pubmed:owner |
NLM
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| pubmed:authorsComplete |
Y
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| pubmed:pagination |
6254-7
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| pubmed:year |
2005
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| pubmed:articleTitle |
Bis-calix[4]arenes bridged by an electroactive tetrathiafulvalene unit.
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| pubmed:affiliation |
Laboratoire de Chimie et Ingénierie Moléculaire des Matériaux d'Angers (CIMMA), Groupe Synthèse Organique et Matériaux Fonctionnels (SOMaF), UMR CNRS 6200, Université d'Angers, 2 Bd Lavoisier, F-49045 Angers, France.
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| pubmed:publicationType |
Journal Article
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