16038511

Source:http://linkedlifedata.com/resource/pubmed/id/16038511

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Predicate	Object
rdf:type	pubmed:Citation
lifeskim:mentions	umls-concept:C0016315, umls-concept:C0028013, umls-concept:C0043309, umls-concept:C0220806, umls-concept:C1280500, umls-concept:C2827424
pubmed:issue	7
pubmed:dateCreated	2005-7-25
pubmed:abstractText	The nickel Kalpha spectra of oxides, halides (NiF2, K2NiF6, NiCl2, NiBr2), complex compounds, and metal are measured with two different double-crystal X-ray fluorescence spectrometers. The peak shifts and line width changes due to the changes in the chemical states are reported. High reproducibility has been shown for the chemical shift and line width measurements. The DV-Xalpha molecular orbital calculation at the ground and the 1s(-1) hole states was performed to prove that the chemical effect originats from the charge-transfer mechanism.
pubmed:language	eng
pubmed:journal	http://linkedlifedata.com/resource/pubmed/journal/8511078
pubmed:status	PubMed-not-MEDLINE
pubmed:month	Jul
pubmed:issn	0910-6340
pubmed:author	pubmed-author:KawaiJunJ, pubmed-author:KonishiTokuzoT, pubmed-author:OhtaMichiharuM
pubmed:issnType	Print
pubmed:volume	21
pubmed:owner	NLM
pubmed:authorsComplete	Y
pubmed:pagination	865-8
pubmed:year	2005
pubmed:articleTitle	Chemical effects in high-resolution nickel Kalpha X-ray fluorescence spectra.
pubmed:affiliation	Department of Materials Science and Engineering, Kyoto University, Sakyo-ku, Kyoto 606-8501, Japan.
pubmed:publicationType	Journal Article