| pubmed-article:16003820 | rdf:type | pubmed:Citation | lld:pubmed |
| pubmed-article:16003820 | lifeskim:mentions | umls-concept:C0019602 | lld:lifeskim |
| pubmed-article:16003820 | lifeskim:mentions | umls-concept:C1511790 | lld:lifeskim |
| pubmed-article:16003820 | lifeskim:mentions | umls-concept:C0851285 | lld:lifeskim |
| pubmed-article:16003820 | lifeskim:mentions | umls-concept:C1177210 | lld:lifeskim |
| pubmed-article:16003820 | lifeskim:mentions | umls-concept:C1513371 | lld:lifeskim |
| pubmed-article:16003820 | lifeskim:mentions | umls-concept:C0242414 | lld:lifeskim |
| pubmed-article:16003820 | pubmed:issue | 18 | lld:pubmed |
| pubmed-article:16003820 | pubmed:dateCreated | 2005-9-6 | lld:pubmed |
| pubmed-article:16003820 | pubmed:abstractText | The association of various alpha-amino acids with four new, coordinatively unsaturated metal complexes ([Cu(5)]2+, [Cu(6)]2+, [Cu(7)]2+, and [Zn(8)]2+) was examined. The receptors [Cu(5)]2+ and [Cu(7)]2+ were found to discriminate histidine (His) from other zwitterionic alpha-amino acids by means of indicator-displacement assays (IDAs) using 5(6)-carboxyfluorescein as an indicator in buffered methanol/water (3:1) solvent. The colorimetric detection of His was achieved by using this IDA method, which appears to owe its selectivity to a unique process involving disruption of the host complex to form a 2:1 His/Cu(II) complex rather than simple indicator displacement. The occurrence of distinct intermolecular coordination processes in response to the introduction of a different amino acid is observed. X-ray crystal structures of the host metal complexes were obtained and exhibit the adoption of a variety of coordination geometries about the metal center. | lld:pubmed |
| pubmed-article:16003820 | pubmed:language | eng | lld:pubmed |
| pubmed-article:16003820 | pubmed:journal | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:16003820 | pubmed:citationSubset | IM | lld:pubmed |
| pubmed-article:16003820 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:16003820 | pubmed:chemical | http://linkedlifedata.com/r... | lld:pubmed |
| pubmed-article:16003820 | pubmed:status | MEDLINE | lld:pubmed |
| pubmed-article:16003820 | pubmed:month | Sep | lld:pubmed |
| pubmed-article:16003820 | pubmed:issn | 0947-6539 | lld:pubmed |
| pubmed-article:16003820 | pubmed:author | pubmed-author:LynchVincent... | lld:pubmed |
| pubmed-article:16003820 | pubmed:author | pubmed-author:AnslynEric... | lld:pubmed |
| pubmed-article:16003820 | pubmed:author | pubmed-author:Folmer-Anders... | lld:pubmed |
| pubmed-article:16003820 | pubmed:issnType | Print | lld:pubmed |
| pubmed-article:16003820 | pubmed:day | 5 | lld:pubmed |
| pubmed-article:16003820 | pubmed:volume | 11 | lld:pubmed |
| pubmed-article:16003820 | pubmed:owner | NLM | lld:pubmed |
| pubmed-article:16003820 | pubmed:authorsComplete | Y | lld:pubmed |
| pubmed-article:16003820 | pubmed:pagination | 5319-26 | lld:pubmed |
| pubmed-article:16003820 | pubmed:dateRevised | 2009-8-4 | lld:pubmed |
| pubmed-article:16003820 | pubmed:meshHeading | pubmed-meshheading:16003820... | lld:pubmed |
| pubmed-article:16003820 | pubmed:meshHeading | pubmed-meshheading:16003820... | lld:pubmed |
| pubmed-article:16003820 | pubmed:meshHeading | pubmed-meshheading:16003820... | lld:pubmed |
| pubmed-article:16003820 | pubmed:meshHeading | pubmed-meshheading:16003820... | lld:pubmed |
| pubmed-article:16003820 | pubmed:meshHeading | pubmed-meshheading:16003820... | lld:pubmed |
| pubmed-article:16003820 | pubmed:meshHeading | pubmed-meshheading:16003820... | lld:pubmed |
| pubmed-article:16003820 | pubmed:meshHeading | pubmed-meshheading:16003820... | lld:pubmed |
| pubmed-article:16003820 | pubmed:year | 2005 | lld:pubmed |
| pubmed-article:16003820 | pubmed:articleTitle | "Naked-eye" detection of histidine by regulation of Cu(II) coordination modes. | lld:pubmed |
| pubmed-article:16003820 | pubmed:affiliation | Department of Chemistry and Biochemistry, The University of Texas at Austin, Austin, TX 78701, USA. | lld:pubmed |
| pubmed-article:16003820 | pubmed:publicationType | Journal Article | lld:pubmed |
| pubmed-article:16003820 | pubmed:publicationType | Research Support, U.S. Gov't, P.H.S. | lld:pubmed |
| pubmed-article:16003820 | pubmed:publicationType | Research Support, Non-U.S. Gov't | lld:pubmed |
| pubmed-article:16003820 | pubmed:publicationType | Research Support, N.I.H., Extramural | lld:pubmed |
