Linked Life Data

15957060

Source:http://linkedlifedata.com/resource/pubmed/id/15957060

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
12
pubmed:dateCreated
2005-6-15
pubmed:abstractText
The syntheses of potassium 2-(2'-methoxynaphth-1'-yl)-3,4-dimethyl-5-phenylphospholide 4 and eta5-pentamethylcyclopentadienyl(eta5-2-(2-methoxynaphth-1-yl)-3,4-dimethyl-5-phenylphospholyl)-ruthenium(II)5 and -iron(II)6 are described. The barrier to rotation of the naphthyl group (79 kJ mol-1 and 72 kJ mol-1 in CD2Cl2 respectively) characterises 5 and 6 as potential tropos type ligands. Coordination of 5 to [PtCl2(PEt3)] gives two cis and two trans complexes [PtCl2(PEt3)5] wherein rotation about the phospholyl-naphthyl vector is slow.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Jun
pubmed:issn
1477-9226
pubmed:author
pubmed:issnType
Print
pubmed:day
21
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
2173-81
pubmed:year
2005
pubmed:articleTitle
Synthesis, structure and dynamics of methoxynaphthalene-substituted phospha-ruthenocenes and -ferrocenes.
pubmed:affiliation
CNRS UMR 7653, DCPH Ecole Polytechnique, 91128, Palaiseau cedex, France. Duncan.Carmichael@polytechnique.fr
pubmed:publicationType
Journal Article