Source:http://linkedlifedata.com/resource/pubmed/id/15957048
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
12
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| pubmed:dateCreated |
2005-6-15
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| pubmed:abstractText |
The synthesis of a cyclometallated Pt(II) thiolate carbonyl complex Pt(thpy)(CO)(mts), (thpy = 2-(2'-thienyl)-pyridinate, mts = methylthiosalicylate) is reported. A combination of emission and time-resolved infrared (TRIR) techniques revealed for both Pt(thpy)(CO)(mts) and its chloride analogue Pt(thpy)(CO)Cl the predominant intra 2-(2'-thienyl)-pyridinate 3pi pi* character of the lowest electronic excited state. The unusually short lifetime (780 ps) of the intraligand 3pi pi* lowest excited state of Pt(thpy)(CO)(mts) indicates that this electronic state is influenced by another close-lying excited state, probably charge-transfer in origin.
|
| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
|
| pubmed:month |
Jun
|
| pubmed:issn |
1477-9226
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| pubmed:author | |
| pubmed:issnType |
Print
|
| pubmed:day |
21
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| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
|
| pubmed:pagination |
2092-7
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| pubmed:year |
2005
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| pubmed:articleTitle |
Pt(II) mono-carbonyl complexes of a cyclometallating 2-(2'-thienyl)-(pyridinato-C,3N') ligand: nature and dynamics of the lowest excited state of the chloro- and thiolato-complexes.
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| pubmed:affiliation |
School of Chemistry, University of Nottingham, Nottingham, UK NG7 2RD.
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| pubmed:publicationType |
Journal Article
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