Linked Life Data

15957032

Source:http://linkedlifedata.com/resource/pubmed/id/15957032

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
23
pubmed:dateCreated
2005-6-15
pubmed:abstractText
A novel two-dimensional cyanide-bridged polymer [CuII(tren)]{CuI[W(V)(CN)8]} . 1.5H2O (tren = tris(2-aminoethyl)amine) formed via the simultaneous in situ metal-ligand redox reaction of [Cu(tren)(OH2)]2+ and self-assembly with [W(V)(CN)8]3- consists of a {CuI[W(V)(CN)8]} square grid built of CuI centres of tetrahedral geometry coordinatively saturated by CN bridges and [W(V)(CN)8]3- capped by [CuII(tren)]2+ moieties; it exhibits ferromagnetic coupling J1 = +5.8(1) cm(-1) within the CuII-W(V) dinuclear subunits and weak antiferromagnetic coupling J2 = -0.03(1) cm(-1) between them through diamagnetic CuI spacers.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Jun
pubmed:issn
1359-7345
pubmed:author
pubmed:issnType
Print
pubmed:day
21
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
2939-41
pubmed:year
2005
pubmed:articleTitle
An unprecedented copper(I,II)-octacyanotungstate(V) 2-D network: crystal structure and magnetism of [CuII(tren)]{CuI[W(V)(CN)8]} . 1.5H2O.
pubmed:affiliation
Faculty of Chemistry, Jagiellonian University, Ingardena 3, 30-060 Krakow, Poland.
pubmed:publicationType
Journal Article