Source:http://linkedlifedata.com/resource/pubmed/id/15954753
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
24
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| pubmed:dateCreated |
2005-6-15
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| pubmed:abstractText |
In this work, we observed a spin-crossover phenomenon in a cesium iron hexacyanochromate, which is a Prussian blue analogue. This compound showed a thermal phase transition with transition temperatures of 211 K (T1/2 downward arrow) and 238 K (T1/2 upward arrow) due to a spin-crossover on FeII sites. This spin-crossover phase transition is accompanied by a lattice contraction of 0.38 A, but maintains a face-centered cubic structure (F3m). This is the first observation of FeII spin-crossover in a series of Prussian blue analogues.
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
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| pubmed:month |
Jun
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| pubmed:issn |
0002-7863
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| pubmed:author | |
| pubmed:issnType |
Print
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| pubmed:day |
22
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| pubmed:volume |
127
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| pubmed:owner |
NLM
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| pubmed:authorsComplete |
Y
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| pubmed:pagination |
8590-1
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| pubmed:dateRevised |
2008-1-17
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| pubmed:year |
2005
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| pubmed:articleTitle |
Observation of an Fe(II) spin-crossover in a cesium iron hexacyanochromate.
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| pubmed:affiliation |
Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan.
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| pubmed:publicationType |
Journal Article
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