15932319

Source:http://linkedlifedata.com/resource/pubmed/id/15932319

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Predicate	Object
rdf:type	pubmed:Citation
lifeskim:mentions	umls-concept:C0022634, umls-concept:C0184661, umls-concept:C0205352
pubmed:issue	12
pubmed:dateCreated	2005-6-3
pubmed:abstractText	The catalytic hydrosilylation of highly hindered and functionalized ketones is described. The combination of inexpensive catalyst precursors, CuCl and NHC.HX (NHC = N-heterocyclic carbene), leads to a highly efficient reduction mediator for the preparation of silyl ethers from unfunctionalized and functionalized alkyl, cyclic, bicyclic, aromatic, and heteroaromatic ketones. A series of catalyst precursors have been structurally characterized and a catalyst-structure activity relationship is discussed.
pubmed:language	eng
pubmed:journal	http://linkedlifedata.com/resource/pubmed/journal/2985193R
pubmed:status	PubMed-not-MEDLINE
pubmed:month	Jun
pubmed:issn	0022-3263
pubmed:author	pubmed-author:Díez-GonzálezSilviaS, pubmed-author:KaurHarneetH, pubmed-author:NolanSteven PSP, pubmed-author:StevensEdwin DED, pubmed-author:ZinnFabiano KauerFK
pubmed:issnType	Print
pubmed:day	10
pubmed:volume	70
pubmed:owner	NLM
pubmed:authorsComplete	Y
pubmed:pagination	4784-96
pubmed:year	2005
pubmed:articleTitle	A simple and efficient copper-catalyzed procedure for the hydrosilylation of hindered and functionalized ketones.
pubmed:affiliation	Department of Chemistry, University of New Orleans, New Orleans, Louisiana 70148, USA.
pubmed:publicationType	Journal Article