15917900

Source:http://linkedlifedata.com/resource/pubmed/id/15917900

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Predicate	Object
rdf:type	pubmed:Citation
lifeskim:mentions	umls-concept:C0007382, umls-concept:C0332514, umls-concept:C1710360
pubmed:issue	11
pubmed:dateCreated	2005-5-26
pubmed:abstractText	Novel chiral Robson-type macrocyclic complexes M(2)-L [where M = Mn(II), Mn(III), Co(II) and Co(III) and L denotes tetra-Schiff base chiral ligands, L1 or L2] have been synthesized by metal template condensation of 2,6-diformyl-4-methyl-phenol, with 1R,2R-diaminocyclohexane (L1) or 1R,2R-diphenylethylenediamine (L2). The dinuclear Co(II) and Co(III) complexes catalyze asymmetric cyclopropanation of styrene with diazoacetate cooperatively and with high enantioselectivity.
pubmed:language	eng
pubmed:journal	http://linkedlifedata.com/resource/pubmed/journal/101154995
pubmed:citationSubset	IM
pubmed:chemical	http://linkedlifedata.com/resource/pubmed/chemical/Propane
pubmed:status	MEDLINE
pubmed:month	Jun
pubmed:issn	1477-0520
pubmed:author	pubmed-author:GaoJianJ, pubmed-author:WoolleyF RossFR, pubmed-author:ZingaroRalph ARA
pubmed:issnType	Print
pubmed:day	7
pubmed:volume	3
pubmed:owner	NLM
pubmed:authorsComplete	Y
pubmed:pagination	2126-8
pubmed:dateRevised	2006-11-15
pubmed:meshHeading	pubmed-meshheading:15917900-Catalysis, pubmed-meshheading:15917900-Cyclization, pubmed-meshheading:15917900-Models, Molecular, pubmed-meshheading:15917900-Propane, pubmed-meshheading:15917900-Stereoisomerism
pubmed:year	2005
pubmed:articleTitle	Catalytic asymmetric cyclopropanation at a chiral platform.
pubmed:affiliation	Department of Radiology, University of Texas Health Science Center-San Antonio, Texas 78229-3900, USA. gao2@uthscsa.edu
pubmed:publicationType	Journal Article, Research Support, Non-U.S. Gov't