Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
6
pubmed:dateCreated
2005-5-23
pubmed:abstractText
Catalytic wet air oxidation (CWAO) of o-chlorophenol in wastewater was studied in a stainless steel autoclave using four different Fe catalysts in the temperature range of 100-200 degrees C. Experimental results showed that high rate of o-chlorophenol and COD(Cr) (Chemical Oxygen Demand, mg/L) removal by CWAO was obtained at relatively low temperature and pressure. The catalysts Fe2(SO4)3, FeSO4, Fe2O3 and FeCl3 all exhibited high catalytic activity. More than 93.7% of the initial COD(Cr) and nearly 100% of o-chlorophenol were removed at 150 degrees C after 150 min with FeSO4 as catalyst. The CWAO of o-chlorophenol was found to be pseudo-first order reaction with respect to o-chlorophenol, with activation energy of 75.56 kJ/mol in the temperature range of 100-175 degrees C.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Jun
pubmed:issn
1673-1581
pubmed:author
pubmed:issnType
Print
pubmed:volume
6
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
569-73
pubmed:dateRevised
2008-11-20
pubmed:meshHeading
pubmed:year
2005
pubmed:articleTitle
Fe salts as catalyst for the wet oxidation of o-chlorophenol.
pubmed:affiliation
Department of Environmental Engineering, Zhejiang University, Hangzhou 310027, China. xhxu@hzcnc.com
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't