Source:http://linkedlifedata.com/resource/pubmed/id/15877413
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| Predicate | Object |
|---|---|
| rdf:type | |
| lifeskim:mentions | |
| pubmed:issue |
10
|
| pubmed:dateCreated |
2005-5-9
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| pubmed:abstractText |
Aerobic reactions of Co(O(2)CMe)(2).4H(2)O with di-2-pyridyl ketone oxime (Hpko) in the presence of counterions (ClO(4)(-), PF(6-)) give the tetranuclear, mixed-valence cobalt(II/III) clusters [Co(II)(2)Co(III)(2)(OR)(2)(O(2)CMe)(2)(pko)(4)S(2)]X(2) [R = H, S = MeOH, X = ClO(4) (1); R = Me, S = EtOH, X = PF(6) (2)] depending on the solvent mixture. Complexes 1 and 2 are the first Co members in the family of metallacrowns adopting the extremely rare inverse 12-metallacrown-4 motif.
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| pubmed:language |
eng
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| pubmed:journal | |
| pubmed:status |
PubMed-not-MEDLINE
|
| pubmed:month |
May
|
| pubmed:issn |
0020-1669
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| pubmed:author |
pubmed-author:DionyssopoulouStavroulaS,
pubmed-author:EfthymiouGeorgiosG,
pubmed-author:EscuerAlbertA,
pubmed-author:KyritsisPanayotisP,
pubmed-author:PerlepesSpyros PSP,
pubmed-author:RaptopoulouCatherine PCP,
pubmed-author:StamatatosTheocharis CTC,
pubmed-author:TerzisArisA,
pubmed-author:VicenteRamonR
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| pubmed:issnType |
Print
|
| pubmed:day |
16
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| pubmed:volume |
44
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| pubmed:owner |
NLM
|
| pubmed:authorsComplete |
Y
|
| pubmed:pagination |
3374-6
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| pubmed:year |
2005
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| pubmed:articleTitle |
The first cobalt metallacrowns: preparation and characterization of mixed-valence cobalt(II/III), inverse 12-metallacrown-4 complexes.
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| pubmed:affiliation |
Department of Chemistry, University of Patras, Greece.
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| pubmed:publicationType |
Journal Article
|