Source:http://linkedlifedata.com/resource/pubmed/id/15852847
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Predicate | Object |
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rdf:type | |
lifeskim:mentions | |
pubmed:issue |
2
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pubmed:dateCreated |
2005-4-27
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pubmed:abstractText |
The B 1pi(u) electronic state of Na2 was excited by the 441.6 nm He-Cd laser line. The Na atomic transitions and the A 1sigma(u)+ --> X 1sigma(g)+ band of Na2 were recorded. From the intensities and spectra of the Na and Na2 fluorescence several collisional processes in the excited sodium atom-dimer system were identified. The Na atomic lines are the result of collisional energy transfer from Na2 (B 1pi(u)) to Na(3P). Predissociation process may also contribute to atomic fluorescence. The A 1sigma(u)+ --> X 1sigma(g)+ band is interpreted through a populating mechanism involving collisional transfer from B 1pi(u) to 2 1sigma(g)+ followed by a radiative transfer to the A 1sigma(u)+ state. From the decay constants and fluorescence intensities, the rate coefficient at 360 degrees C for collisional energy transfer from Na2 (B 1pi(u)) to Na2 (2 1sigma(g)+) was found to be 5.7 x 10(-10) cm3 x s(-1). The predissociation rate of the B 1pi(u) is 2.7 x 10(6) s(-1).
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pubmed:language |
chi
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pubmed:journal | |
pubmed:citationSubset |
IM
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pubmed:chemical | |
pubmed:status |
MEDLINE
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pubmed:month |
Feb
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pubmed:issn |
1000-0593
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pubmed:author | |
pubmed:issnType |
Print
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pubmed:volume |
25
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pubmed:owner |
NLM
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pubmed:authorsComplete |
Y
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pubmed:pagination |
171-3
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pubmed:meshHeading |
pubmed-meshheading:15852847-Algorithms,
pubmed-meshheading:15852847-Energy Transfer,
pubmed-meshheading:15852847-Kinetics,
pubmed-meshheading:15852847-Models, Chemical,
pubmed-meshheading:15852847-Sodium,
pubmed-meshheading:15852847-Spectrometry, Fluorescence,
pubmed-meshheading:15852847-Thermodynamics
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pubmed:year |
2005
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pubmed:articleTitle |
[Collisional excitation transfer between Na2(B 1pi(u)) and Na2(2 1sigma(g)+)].
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pubmed:affiliation |
Department of Physics, Xinjiang University, Urumqi 830046, China.
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pubmed:publicationType |
Journal Article,
English Abstract,
Research Support, Non-U.S. Gov't
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