Linked Life Data

15835148

Source:http://linkedlifedata.com/resource/pubmed/id/15835148

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
7
pubmed:dateCreated
2005-4-19
pubmed:abstractText
One-electron oxidation of various biphenyl derivatives such as biphenyl (BP), 4-hydroxybiphenyl (HBP), 4,4'-biphenol (DHBP), 4-methoxy-4'-hydroxybiphenyl (MHBP), 4-cyano-4'-hydroxybiphenyl (CNHBP), 4-biphenylmethanol (BPM), and 4-biphenylethanol (BPE) adsorbed on the surface of TiO2 powder slurried in acetonitrile has been investigated by time-resolved diffuse reflectance spectroscopy. From the Langmuir adsorption isotherms for BP and HBP, it is suggested that the OH group plays an important role in adsorbing on the surface ofTiO2. The spectroscopic characteristics of charge transfer complexes of substrates and the TiO2 surface have been studied by steady-state diffuse reflectance spectroscopy. The high efficiency of a one-electron oxidation reaction was observed for hydroxyl-substituted BPs (HBP, DHBP, MHBP, CNHBP), compared with BPM and BPE, indicating that the strength of the electronic coupling element (H(DA)) between the electron acceptor and donor is a key factor in the one-electron oxidation of a substrate adsorbed on the TiO2 powder. The effects of the distance between the electron donor and the acceptor on the electronic coupling element are also discussed.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Mar
pubmed:issn
0743-7463
pubmed:author
pubmed:issnType
Print
pubmed:day
30
pubmed:volume
20
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
2753-9
pubmed:dateRevised
2006-11-15
pubmed:meshHeading
pubmed:year
2004
pubmed:articleTitle
Photocatalytic one-electron oxidation of biphenyl derivatives strongly coupled with the TiO2 surface.
pubmed:affiliation
The Institute of Scientific and Industrial Research (SANKEN), Osaka University, Mihogaoka 8-1, Ibaraki, Osaka 567-0047, Japan.
pubmed:publicationType
Journal Article, Research Support, Non-U.S. Gov't