Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
7
pubmed:dateCreated
2005-4-19
pubmed:abstractText
We measured the adsorption characteristics of trinitrotoluene (TNT) on piezoresistive silicon microcantilever surfaces under ambient air using a well-characterized TNT vapor generator. This allowed us to quantify the adsorption parameters and to estimate the sticking coefficient. The sticking coefficient initially increases with TNT exposure time and then levels off around 0.3. Atomic force microscopy images of silicon surfaces exposed to TNT revealed "island" formation of the adsorbate on the silicon surface. At low exposure times, mainly the number density of islands increased with exposure time; at longer exposure times, the size (in particular, height) of the islands grew, corresponding to the higher sticking coefficients. These observations can be qualitatively explained via the difference between TNT-surface and TNT-TNT interactions mediated by water molecules.
pubmed:language
eng
pubmed:journal
pubmed:citationSubset
IM
pubmed:chemical
pubmed:status
MEDLINE
pubmed:month
Mar
pubmed:issn
0743-7463
pubmed:author
pubmed:issnType
Print
pubmed:day
30
pubmed:volume
20
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
2690-4
pubmed:dateRevised
2006-11-15
pubmed:meshHeading
pubmed:year
2004
pubmed:articleTitle
Adsorption of trinitrotoluene on uncoated silicon microcantilever surfaces.
pubmed:affiliation
Oak Ridge National Laboratory, P.O. Box 2008, Oak Ridge, Tennessee 37831-6122, USA.
pubmed:publicationType
Journal Article, Research Support, U.S. Gov't, Non-P.H.S.