15796509

Source:http://linkedlifedata.com/resource/pubmed/id/15796509

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Predicate	Object
rdf:type	pubmed:Citation
lifeskim:mentions	umls-concept:C0205173, umls-concept:C0220781, umls-concept:C0302917, umls-concept:C0700114, umls-concept:C1880022, umls-concept:C1883254
pubmed:issue	13
pubmed:dateCreated	2005-3-30
pubmed:abstractText	The first example of a stable oxoborane monomer (LB=O) stabilized by complexation to AlCl3 has been prepared by the reaction of LAlCl2 with BCl3 followed by treatment with H2O in CH2Cl2 (L = [HC(CMe)2(NC6F5)2]). DFT calculations reveal that considerable boron-oxygen double bond character is retained in this complex.
pubmed:language	eng
pubmed:journal	http://linkedlifedata.com/resource/pubmed/journal/7503056
pubmed:status	PubMed-not-MEDLINE
pubmed:month	Apr
pubmed:issn	0002-7863
pubmed:author	pubmed-author:CowleyAlan HAH, pubmed-author:JonesJamie NJN, pubmed-author:MooreJennifer AJA, pubmed-author:VidovicDragoslavD
pubmed:issnType	Print
pubmed:day	6
pubmed:volume	127
pubmed:owner	NLM
pubmed:authorsComplete	Y
pubmed:pagination	4566-7
pubmed:dateRevised	2008-1-17
pubmed:year	2005
pubmed:articleTitle	Synthesis and characterization of a coordinated oxoborane: Lewis acid stabilization of a boron-oxygen double bond.
pubmed:affiliation	Department of Chemistry and Biochemistry, The University of Texas at Austin, 1 University Station A5300, Austin, TX 78712-0165, USA.
pubmed:publicationType	Journal Article