15787585

Source:http://linkedlifedata.com/resource/pubmed/id/15787585

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Predicate	Object
rdf:type	pubmed:Citation
lifeskim:mentions	umls-concept:C0014898, umls-concept:C0220781, umls-concept:C0332514, umls-concept:C0936012, umls-concept:C1883254
pubmed:issue	7
pubmed:dateCreated	2005-3-24
pubmed:abstractText	[reaction: see text] Synthesis of enantiomerically pure beta-amino-alpha-hydroxy esters (1, 2) and beta-amino-alpha-azido ester (3) using Sharpless AA as a key step is described. A hitherto unreported side reaction, the oxidation of the beta-hydroxy-alpha-amino ester (5) into the alpha,alpha-di-tert-butyloxycarbamoyl-beta-ketoester (8) under AA conditions, is documented.
pubmed:language	eng
pubmed:journal	http://linkedlifedata.com/resource/pubmed/journal/2985193R
pubmed:status	PubMed-not-MEDLINE
pubmed:month	Apr
pubmed:issn	0022-3263
pubmed:author	pubmed-author:Bois-ChoussyMichèleM, pubmed-author:JiaYanxingY, pubmed-author:LiuZuoshengZ, pubmed-author:MaNianchunN, pubmed-author:MalabarbaAdrianoA, pubmed-author:ZhuJiepingJ
pubmed:issnType	Print
pubmed:day	1
pubmed:volume	70
pubmed:owner	NLM
pubmed:authorsComplete	Y
pubmed:pagination	2847-50
pubmed:year	2005
pubmed:articleTitle	Synthesis of beta-amino-alpha-hydroxy esters and beta-amino-alpha-azido ester by Sharpless asymmetric aminohydroxylation, byproducts analysis.
pubmed:affiliation	Institut de Chimie des Substances Naturelles, CNRS, 91198 Gif-sur-Yvette Cedex, France.
pubmed:publicationType	Journal Article