Linked Life Data

15760126

Source:http://linkedlifedata.com/resource/pubmed/id/15760126

Statements in which the resource exists as a subject.
PredicateObject
rdf:type
lifeskim:mentions
pubmed:issue
6
pubmed:dateCreated
2005-3-11
pubmed:abstractText
[reaction: see text] The aryl fluoride bond has long been considered inert toward Pd-catalyzed insertion reactions. This paper reports for the first time that aryl fluorides bearing an o-carboxylate group can undergo Pd-catalyzed couplings. On the basis of this computational study and subsequent experimental verifications of its predictions, we herein report that such reactions are facilitated by stabilization of the transition state by proximal oxyanions.
pubmed:language
eng
pubmed:journal
pubmed:status
PubMed-not-MEDLINE
pubmed:month
Mar
pubmed:issn
1523-7060
pubmed:author
pubmed:issnType
Print
pubmed:day
17
pubmed:volume
7
pubmed:owner
NLM
pubmed:authorsComplete
Y
pubmed:pagination
1011-4
pubmed:year
2005
pubmed:articleTitle
Proximity effects in the palladium-catalyzed substitution of aryl fluorides.
pubmed:affiliation
Chemical Research and Development, Pfizer Global R&D-La Jolla, 10578 Science Center Drive, San Diego, California 92121, USA. sami.bahmanyar@pfizer.com
pubmed:publicationType
Journal Article